Nice idea, I think it might be a bit to subtle, but do let us know the results.
I've tried something similar, see my Henschel Hs 129. I still believe black works well, even under darker top colours, but the judgement has to be just right and the paint applied thinly. With my next batch of models I'm going to try something else. The undersides will recieve a black preshading, The uppersurfaces will be "pre-shaded" with the top colour, then that colour will have a couple of drops of white added and the panels filled in with that mix. That's the basic idea anyway, I have to try it out before deciding if it works or not. The big difference with this method is that the "pre-shading" is not covered. Well it can be depends how the altered colour is, I reckon it will be advantages to "fill in" the panel then gave a light overspray to the "pre-shaded" areas. I'm not really a convert to "scale" colour theory, which is what this method angles towards. The answer to that would be to darken the colour for the "pre-shading then use the original colour to fill in. I think that way will prove to dark and as you can't darken with, say black, and expect to get the colour back by adding white you would end up wasting paint.
Mal